Are there nonstop flights from Port of Spain (POS) to Amsterdam (AMS)?

Yes. KLM fly this route. Flight time is about 9h 17m.

What is the fastest connection from Port of Spain (POS) to Amsterdam (AMS)?

via Bridgetown ≈ 9h 47m, via London ≈ 9h 47m, via Sint Maarten ≈ 10h 9m (estimated flying time, excluding layovers).

from 35,000 ANA miles (economy, one way, based on the published award charts).

Piarco International Airport (POS) to Amsterdam Airport Schiphol (AMS)・7,462 km

Nonstop flights available (1 airline). Flight time about 9h 17m. Nonstop return flights also operate.

With milesANA 35,000 miles+ (via EWR)Economy, one way, estimate. Tap a connection for miles by cabin.

13 one-stop options, sorted by estimated flying time. Tap one to see the airlines on each leg and booking links.

Times are estimated from distance. Check schedules, frequency and availability with the airline or a booking site.